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Intramolecular Oxidative Addition Triggered by One-Electron Oxidation of Molybdenum( iii ) Tris(anilide): Generation of Molybdenum(v) Imido Aryl Bis(anilide) by Autocatalysis

https://doi.org/10.1021/acs.organomet.3c00502

Paparo, Albert; Schindler, Tobias; van_Leusen, Jan; Cook, Jessica; Spaniol, Thomas P; Kögerler, Paul; Temprado, Manuel; Cummins, Christopher C; Okuda, Jun (February 2025, Organometallics)

Free, publicly-accessible full text available February 10, 2026
Reactivity of the molecular magnesium hydride cation [MgH]+ supported by an NNNN macrocycle

https://doi.org/10.1016/j.poly.2019.114331

Lemmerz, Lara E.; Wong, Anthony; Menard, Gabriel; Spaniol, Thomas P.; Okuda, Jun (December 2020, Polyhedron)
null (Ed.)
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Cationic magnesium hydride [MgH] ⁺ stabilized by an NNNN-type macrocycle

https://doi.org/10.1039/C9CC00490D

Lemmerz, Lara E.; Mukherjee, Debabrata; Spaniol, Thomas P.; Wong, Anthony; Ménard, Gabriel; Maron, Laurent; Okuda, Jun (March 2019, Chemical Communications)

A magnesium hydride cation [(L)MgH] + supported by a macrocyclic ligand (L = Me 4 TACD; 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) has been prepared by partial protonolysis of a mixed amide hydride [(L)MgH 2 Mg{N(SiMe 3 ) 2 } 2 ] and shown to undergo a variety of reactions with unsaturated substrates, including pyridine.
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